To use ADSync using SSL make sure that LDAP-S is configured on the Cloud Active Directory, to accept and allow communication using ldaps.
General Info sharing for LDAP-S configuraiton on DC
http://support.microsoft.com/kb/321051
How to enable LDAP over SSL with a third-party certification authority
http://social.technet.microsoft.com/wiki/contents/articles/2980.ldap-over-ssl-ldaps-certificate.aspx Verification Ldaps communication:
To verify if secure ldaps is establishing connection with remote Cloud AD.
On Customer Local AD machine where HC ADSync utility is running go to start > Run > type (without quote) "
ldp" > Connection tab > connect.
Server : Insert the Cloud DC URL name on which certificate is installed
Port : 636
SSL : Enable this option